oh hell there's a lot going on here as there is also impedance matching for your headphones @ 25ohm I suspect.
Problem is that your guitar has a hi-impedance output between 250k-1m config dependent @ +- 50mv which is suitable for the amps input and now you're inserting an 25ohm @ +- .5 - 2v ieeesh wenna will cook something eventually
Not Ideal but if you simply want to drop the line out level passively.
1) hook up crude passive variable L-pad attenuator (hi-wattage POT) to help find the ideal level.
Something like this - can place a high pass cap in there to prevent hi-freq loss at low vol
g
2) play with R*65,*66 and/or R67,64, on Gregs schematic (* = mono output) to drop the level.
I will give some thought and come back with pearls of wisdom (i hope) ... Greg please help !!!